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The relationship between pH and pKa is described by the Henderson-Hasselbalch equation.

Once you have pH or pKa values, you know certain things about a solution and how it compares with other solutions:

If you know either pH or pKa, you can solve for the other value using an approximation called the Henderson-Hasselbalch equation:

pH = pKa + log (/)pH = pka+log (/)

pH is the sum of the pKa value and the log of the concentration of the conjugate base divided by the concentration of the weak acid.

At half the equivalence point:

pH = pKa

It's worth noting sometimes this equation is written for the Ka value rather than pKa, so you should know the relationship:

pKa = -logKa

The reason the Henderson-Hasselbalch equation is an approximation is because it takes water chemistry out of the equation. This works when water is the solvent and is present in a very large proportion to the and acid/conjugate base. You shouldn't try to apply the approximation for concentrated solutions. Use the approximation only when the following conditions are met:

Find for a solution of 0.225 M NaNO2 and 1.0 M HNO2. The Ka value (from a table) of HNO2 is 5.6 x 10-4.

pKa = −log Ka = −log(7.4×10−4) = 3.14

pH = pka + log (/)

pH = pKa + log(/)

pH = 3.14 + log(1/0.225)

pH = 3.14 + 0.648 = 3.788

 = 10−pH = 10−3.788 = 1.6×10−4

The double walled design keeps your chickens warm in winter by trapping a pocket of air in the same way that double glazing does on windows.  There's no need to add dangerous heat lamps or lighting in winter to keep your chickens warm.

What makes chickens cold isn't the ambient temperature, it's the wind. Just like wild birds in Canada, your hens will grow in extra warm feathers in anticipation of winter. As long as your chickens are in a draft/wind free environment, their feathers won't part and expose their skin, cooling them down. Your Eglu Cube has draft-free ventilation that keeps the air fresh without blowing cold air on your birds. In your run, use our clear covers or tarps to keep the wind and snow off.

You'll be amazed how happy your chickens are in winter (even if you're not!). We have found from testing the Eglu Cube in Canada for multiple winters that eggs take much longer to freeze than in our old traditional wooden coops. Less frozen eggs means more eggs for your family to enjoy.

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